Bentonite
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Special offer for Bentonite

This text is to notify you that Marjan Mineral Company is now providing its service in supplying the best Bentonite with several special characteristics in any particle size distribution. This Bentonite has been processed by modern methods to eliminate any silica impurities, reduce Iron and increase Alumina. These are some of its outstanding characteristics:

  • It has only one mineral: Montmorillonite
  • Low amount of Silica and Iron
  • Alumina (Al2O3) enrichment up to 32 percent
  • Very fine particle size
  • Stunning whiteness
  • Very high cohesion

We can supply noodle shaped or caked Bentonite in any tonnage with competitive price with these packages:

  • 25 Kg nylon bags or 1000 Kg shrinked packed pallet
  • 1000 Kg jumbo bag

Please feel free to keep in touch with us about any of your business related requirements/queries.
Chemical analysis of our product is as below:

Sample Re-AB/50 Photo
 SiO2  74.25 % Bentonite exporter, Iran Bentonite exporter, Bentonite Iran Bentonite, Bentonite
 Al2O3  14.69 %
 Fe2O3  1.17 %
 CaO  1.36 %
 Na2O  0.09 %
 K2O  0.08 %
 MgO  2.13 %
 MgO  2.13 %
 TiO2  0.197 %
 P2O5  70.003 %
 SO3  0.002 %
 L.O.I  5.79 %
 Moisture  Content  <5%

Bentonite

Bentonite clay has been used for thousands of years as both an internal and external purification aid. The Egyptians used it to preserve their famous mummies. The ancient Greeks and Romans used it to restore health. The great German naturopaths of the last century hailed clay as one of nature's great remedies. Numerous so-called primitive tribes have used clay for both internal and external purification.

The American Indians were evidently the first to use Bentonite for its adsorptive properties. According to one Indian legend, a deposit of natural clay of miraculous medicinal qualities was used by the medicine men in the Bighorn Mountains of Wyoming and Montana. The Indians called this clay "ee-wah-kee," meaning "the mud that heals". The early pioneers used Bentonite from outcrops called "soap holes" to wash their clothes and to lubricate their wagon wheels (Thorson, undated).

Iranians have known Bentonite and its characteristics since far pasts and used Bentonite as mud shampoo, clay soap and etc. Nowadays Iran has many Bentonite mines and has a great ability to supply Bentonite for other countries. Iran's Bentonites are famous because of their outstanding characteristics. It is MGT Mineral Company's honor that can provide all necessary conditions for Bentonite exporting.   

 

What is Bentonite?

Bentonite clay is a fine-grained rock composed mainly of Montmorillonite minerals. The formation of Bentonite is an in situ alteration of rhyolitic volcanic ash. Pyroclastic material was ejected into the atmosphere by volcanic activity and deposited as sediment in a marine environment. Bentonite clay is composed of microscopic platelets consisting of layers of aluminum hydroxide held between layers of silicate atoms. These platelets are stacked one on top of the other. If a gram of Bentonite were spread out only one particle layer thick, its billions of particles would cover an area greater than a regular football field.

Physical Properties of Montmorillonite
Chemical Formula (Na,Ca)0.3(Al,Mg)2(Si4O10)(OH)2•n(H2O)
Cleavage Perfect on {001}
System Monoclinic
Color White, Gray white, Yellow, Brownish yellow, Greenish yellow
Density 2 - 2.7 g/cm3
Diaphaneity Translucent to Opaque
Fracture Earthy - Dull, clay-like fractures with no visible crystalline affinities, (e.g. howlite).
Tenacity -
Habit Earthy - Dull, clay-like texture with no visible crystalline affinities, (e.g. howlite).
Hardness (Mohs) 1.5-2 - Talc-Gypsum
Luminescence Non-fluorescent
Luster Earthy (Dull)
Streak white
Magnetism Nonmagnetic

There are two basic types of Bentonite, Sodium type and Calcium type:

  • Sodium Bentonite: Because of its high absorbency and clumping tendency, Sodium Bentonite is useful as a sealant. It is considered a safe, natural, nontoxic and inexpensive treatment for porous soils. Its swelling capacity gives Sodium Bentonite the ability to bond with soil and create and impenetrable barrier. Sodium Bentonite is also used for mud drilling, clumping cat litter, and as a bonding agent for feeds, medicines and cosmetics. Currently, Sodium Bentonite is being investigated as an absorbing agent to remove E-Coli bacteria from food.

  • Calcium Bentonite: Calcium Bentonite is referred to as "living clay" because of the belief found in many cultures that it is useful as a medicine. The practice of geophagy or "earth eating" is centered on the belief that some clays such as Calcium Bentonite is able to be safely ingested for the absorption and removal of toxins from the gastrointestinal tract. Geophagy is known to have been practiced by some Indigenous peoples of Australia and Africa. The modern alternative healthcare industry uses Calcium Bentonite extensively for internal and external toxin removal that is believed to be based on ion exchange. Consult your doctor if you are considering ingestion of any non-food substance.

Bentonite Occurrence

Bentonite occurs in sedimentary or volcanic sequences where it forms in-situ by the alteration of volcanic ash or tuff. Alteration processes may include deuteric alteration, hydrothermal alteration and sub-aqueous devitrification.

Most Bentonite deposits form under marine conditions or, less commonly, in alkaline lakes. Andesitic to Rhyolitic volcanic rocks are the most common primary source. The final chemical character of the Bentonite is dependent on the combined influences of the chemistry of the primary rock, the environment in which it was deposited and its post-formation history.

Bentonitic units are commonly laterally extensive strata within volcanogenic sedimentary sequences. They may vary in thickness from a few centimeters to tens of meters, and range from Permian to Pleistocene in age. The most economically important Sodium-Bentonites tend to be associated with Jurassic or younger volcanic rocks. This is because Smectite clays are unstable at higher pressures, and Bentonite is increasingly transformed into mixed Illite–Smectite with increasing depth of burial.

 

Bentonite-producer, Iran Bentonite producer, Bentonite

Economic Classification

Quality requirements for the bentonite depend on purpose (buffer on backfill) and used material. Preliminary required values for the buffer bentonite are presented in below table. The values are set based on current knowledge. The required values may be updated along with increasing amount of information and test data on suitable buffer bentonites.

High-grade Na-Bentonite
   Required average  value  Single test, maximum  value  Single test, minimum  value
 Water content  ≤ 13 %  15 %  6 %
 Swelling index  ≥ 20 ml/2g    15 ml/2g
 Smectite content  ≥ 75 %    65 %
 Liquid limit  ≥ 250 %    200 %
 Cation exchange capacity (CEC)  ≥ 70 mEq/100 g    60 mEq/100 g
 Hydraulic conductivity*  ≤ 10-12 m/s  ≤ 10-11 m/s  
 Swelling pressure*  ≥ 1 MPa and ≤10 MPa    
 Thermal conductivity**  ≥ 1.0 W/m/K    ≥ 1.0 W/m/K
High-grade Ca-Bentonite
 Water content  ≤ 13 %  15 %  6 %
 Swelling index  ≥ 15 ml/2g    10 ml/2g
 Smectite content  ≥ 75 %    65 %
 Liquid limit  ≥ 80 %    60 %
 Cation exchange capacity (CEC)  ≥ 60 mEq/100 g    50 mEq/100 g
 Hydraulic conductivity*  ≤ 10-12 m/s  ≤ 10-11 m/s  
 Swelling pressure*  ≥ 1 MPa and ≤10 MPa    
 Thermal conductivity**  ≥ 1.0 W/m/K    ≥ 1.0 W/m/K

* Dry density of buffer blocks 1655 – 1754 kg/m3
** In dry density of 1655 kg/m3, water content 17 % and degree of saturation 70 % or in dry density of 1754 kg/m3, water content 17 % and degree of saturation 81 %. After saturation thermal conductivity of buffer block should be 1.3 W/m/K (Posiva 2006).

The specifications of bentonite for chemical & rubber and oil-well drilling industries vide IS Specification IS: 6186-1986 (Second Revision Reaffirmed 2010) are given in below table.

BIS Specifications of Bentonite in Chemical, Rubber and Oil - Well Drilling Industries {IS: 6186-1986 (Second Revision, Reaffirmed 2010)}

 
Sl. No. Characteristic  Industry
Type 1 Chemical & Rubber Type 2* Oil-well drilling
High grade Offshore grade
1.  Moisture, % by mass      
   a) Minimum  5.00  -  -
   a) Minimum  12.00  12.00  12.00
2.  pH  9.00 to 10.50   -   - 
3.  Gel formation index  To pass test  To pass test  To pass test
4.  Swelling power  To pass test  -  -
5.  Fineness      
   a) Dry - To pass through 150 micron IS  sieve, % by mass, minimum  -  98.00  98.00
    To pass through 75 micron IS sieve, %     by mass, minimum  95.00  90.00  -
    b) Wet - Retained on 150 micron IS        sieve, % by mass, maximum  0.01  -  -
   To pass through 45 micron IS sieve, %  by  mass, minimum  90.00  98.00  -
6.  Viscosity at 300 C, centipoise, min      
   a) Apparent  -  15.00  -
   b) Plastic  -  6.00  -
7.  Filtration loss, ml, maximum  -  15.00  15.00
   For Rubber Industry Only      
8.  Sand content, % by mass, maximum  -  2.00  2.00
9.  Loss on ignition (other than loss on  drying), % by mass, maximum  6.00  -  -
10.  Matter soluble in water, % by mass,  maximum  4.00  -  -
11.  Copper (as CuO), % by mass, maximum  0.01  -  -
12.  Manganese (as MnO), % by mass,  maximum  0.01  -  -

Specifications for ceramic industry vide IS: 12621-1988 (Reaffirmed 2011) are given in Table-4. BIS has revised the specifications of bentonite for use in foundries; the new specifications are prescribed vide IS: 12446 - 2007 (first Revision, Reaffirmed 2012).

BIS Specifications of Bentonite for Ceramic Industry {IS: 12621-1988 (Second amedment, Reaffirmed 2011)}

Sl. No. Characteristic Requirement
1.   Free moisture content at 105 ± 2oC, % by mass, max  6.0
2.   Residue on 106 micron IS sieve, % by mass, max  Nil
3.   Grit content on 45 micron IS sieve, % by mass, max  1.0
4.   Loss on ignition, % by mass   8 to 12
5.   Silica (as SiO2), % by mass  48 to 55
6.   Alumina (as Al2O3), % by mass  18 to 28
7.   Iron Oxides (as Fe2O3), % by mass, max  4
8.   Titanium oxide (as TiO2), % by mass, max  3
9.   Oxides of iron (as Fe2O3) and titanium (as TiO2) together, % by  mass, min  6
10.   Water of plasticity, % by mass  45 to 60
11.   Swelling power after 24 hours  15 to 20
12.   Calcium oxide (as CaO), % by mass, max  3
13.   Magnesium oxide (as MgO), % by mass, max  3
14.   Oxides of calcium (as CaO) and magnesium (as MgO), together, % by  mass, max  5
15.   Viscosity at 30oC, centipoise, min  4.5

Bentonite Usages:

Bentonite has high swelling properties along with good viscosity and liquid limit. These properties are highly valued in most of the industrial applications. Sodium bentonite is well suited as a binder in the preparation of pellets and in foundry and as oilwell drilling mud. Bentonite also acts as a suspending agent in oil well drilling fluids. Bentonite exhibits good green strength along with high hot and dry strength which helps in preventing moulds from breaking or cracking during the pouring or cooling process in the foundry industry. Owing to high green strength resulting from its property to absorb and then release moisture, bentonite is used in iron ore pelletisation. Sodium-based bentonite of 75 micron size finds suitability in iron ore pelletisation for bonding by user industries. Bentonite clay is also used in pyrotechnics, to make end plugs and rocket engine nozzles.
Applications for Bentonite include:

  • Drilling: Owing to its rheological properties and thixotropy of aqueous suspensions, bentonite is used as a mud constituent for oil and water well drilling. Its functions are mainly to stabilise the borehole, seal the borehole walls, and remove drill cuttings. Bentonite muds are thus employed for oil and water well drilling, tunnel, and microtunnel drilling.
  • Foundry: Bentonite is used as a bonding material in the preparation of moulding sand for the production of cast iron, steel, and non-ferrous casting. The unique properties of bentonite yield green sand moulds with good flowability, compactability, and thermal stability for the production of high quality castings.
  • Surface Coatings: the gel structure in water based Coatings assists the suspension of other Pigments. It also enhances application properties and prevents the applied film from sagging.
  • Paper Industry: White Bentonite MB has the ability to scavenge for organics such as pitches and stickies. It is also used in Retention Aid Systems and to control ink and adhesive penetration.
  • Ceramics: because of its relatively pure nature and stong binding properties, White Bentonite MB can be used to improve the 'green strength' of ceramic bodies.
  • Adhesives and Sealants: gels formed from White Bentonite MB are particularly useful in structuring products which are subject to changes in pH during their manufacture. Applications include toilet cleaners, machine dishwashing liquids, cream cleaners, liquid detergents, oven cleaners and in powder detergents as a natural fabric softener.
  • Civil engineering: Bentonite slurries are used in the construction of special foundations for digging diaphragm walls and bored piles. In geothecnical engineering, bentonite is used for self-hardening mixtures employed to build cut off walls, grouting mortars, and grouting. Finally, bentonite waterproofing properties are best exploited in environmental engineering, to seal off soil infiltrations, and line the base of landfills.
  • Water treatment: Due to its ion exchange, flocculation, and sedimentation properties, bentonite is used in environmental protection for water clarification, and as an aid to polyelectrolites and inorganic flocculants.
  • Agriculture: Bentonite is used as an ion exchanger for soil improvement and conditioning. It is also used for gardening in soil compounds and mixtures to absorb humidity, and as a carrier for various herbicides and pesticides.
  • Cat litter: Owing to its swelling property, bentonite is used for cat litter, due to its advantage of absorbing refuse by forming clumps.
  • Pharmaceuticals, cosmetics, and spa mud therapy: Bentonite is used as a filler in pharmaceuticals, and for its absorption/adsorption functions. It is also employed in creams, face-powders, and spa mud preparations.
  • Detergent additive: Bentonite is used in detergents to soften the fabrics. Liquid cleansers/soaps rely on the inclusion of bentonite as a suspension agent and viscosity enhancer.
 

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